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On the Transport Properties of Li-TFSI Water-in-Salt Electrolytes

preprint
submitted on 20.09.2019 and posted on 24.09.2019 by Zhujie Li, Roza Bouchal, Trinidad Mendez-Morales, Anne-Laure Rollet, Cecile Rizzi, Steven Le Vot, Frédéric Favier, Benjamin Rotenberg, Oleg Borodin, Olivier Fontaine, Mathieu Salanne
Water-in-salts are a new family of electrolytes that may allow the development of aqueous Li-ion batteries. They have a structure which is reminiscent of the one of ionic liquids, and they are characterized by a large concentration of ionic species. In this work we study their transport properties and how they evolve with concentration by using molecular dynamics simulations. We first focus on the choice of the force field. By comparing the simulated viscosities and self diffusion coefficients with experimental measurements, we select a set of parameters that reproduces well the transport properties. We then use the selected force field to study in detail the variations of the self and collective diffusivities of all the species as well as the transport number of the lithium ion. We show that correlation between ions and water play an important role over the whole concentration range. In the water-in-salt regime, the anions form a percolating network which reduces the cation-anion correlations and leads to rather large values for the transport number compared to other standard electrolytes.

Funding

Agence Nationale de la Recherche/ANR-10-LABX-0076

ERC/771294

Department of Energy/IAA SN2020957

History

Email Address of Submitting Author

mathieu.salanne@sorbonne-universite.fr

Institution

Sorbonne University

Country

France

ORCID For Submitting Author

0000-0002-1753-491X

Declaration of Conflict of Interest

No conflict of interest

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in The Journal of Physical Chemistry B

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