ChemRxiv
These are preliminary reports that have not been peer-reviewed. They should not be regarded as conclusive, guide clinical practice/health-related behavior, or be reported in news media as established information. For more information, please see our FAQs.
manuscript.pdf (1.61 MB)
0/0

On the Bonding Situation in Stannocene and Plumbocene N-Heterocyclic Carbene Complexes

preprint
submitted on 24.11.2019 and posted on 29.11.2019 by Diego Andrada, Sergi Danés, Lisa Wirtz, Carsten Mueller, Volker Huch, Theresa Block, Rainer Pöttgen, André Schäfer
A detailed experimental and computational study of a series of stannocene and plumbocene N-heterocyclic carbene complexes is presented. This unique class of group 14 Lewis acid base adducts was obtained from reactions of the corresponding metallocenes and N-heterocyclic carbenes (NHC), and were structurally characterized by single crystal X-ray diffraction. The obtained structures show a perpendicular pose of the NHC with respect to the metallocene, hence precluding the maximal interaction between the moieties. The nature of the Sn-CNHC and Pb-CNHC bonds have been investigated by applying Energy Decomposition Analysis (EDA-NOCV). For the sake of comparison, known stannocene and plumbocene Lewis base complexes have been included in the series. The attractive chemical bonding interactions are around 50% electrostatic, 30% covalent and 20% dispersion. Indeed, dispersion interactions play a determining role the bigger the substituents become. The covalent interactions derive from the donation of the carbene ligand into the empty p orbital of the metallocene.

Funding

ERC Starting grants, EU805113

Emmy Noether-program, SCHA1915/3-1

History

Email Address of Submitting Author

diego.andrada@uni-saarland.de

Institution

Saarland University

Country

Germany

ORCID For Submitting Author

0000-0003-2515-7859

Declaration of Conflict of Interest

The authors declare no competing financial interest.

Exports

Logo branding

Exports