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On-Demand Electrochemical Synthesis of copper(I) Triflate and Its Application in the Aerobic Oxidation of Alcohols

preprint
submitted on 26.01.2021, 16:03 and posted on 27.01.2021, 13:21 by Thomas P. Nicholls, Richard A. Bourne, Bao N. Nguyen, Nikil Kapur, Charlotte Willans

An on-demand electrochemical synthesis of copper(I) triflate under both batch and continuous flow conditions has been developed. A major benefit of the electrochemical methodology is that the only by-product of the reaction is hydrogen gas which obviates the need for work-up and purification, and water is not incorporated into the product. Upon completion of the electrochemical synthesis, solutions are directly transferred or dispensed into reaction mixtures for the catalytic oxidation of alcohols with no requirement for work-up or purification.

Funding

EP/R009406/1

History

Email Address of Submitting Author

c.e.willans@leeds.ac.uk

Institution

University of Leeds

Country

United Kingdom

ORCID For Submitting Author

0000-0003-0412-8821

Declaration of Conflict of Interest

No conflicts of interest

Exports