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Novel copper(I) complex of 2,5-Bis(2-pyridyl)phosphole: Synthesis, Characterization, Catalytic Activity and DFT Calculations

preprint
submitted on 24.01.2021, 15:03 and posted on 27.01.2021, 07:28 by Jeremy Guaramato, Franmerly Fuentes, Rocío Rivera-Campos, Deivi Oliveros, José R. Mora, Andreas Reiber, Edward Ávila, Yomaira Otero, Juan Manuel Garcia Garfido

A copper(I) complex [CuCl{k1(P)-1a}{k2(P,N)-1a}] (1a = 2,5-bis(2-pyridyl)-1-phenylphosphole) with pseudo tetrahedral geometry was synthesized. In solution, 1a displays a hemilabile behaviour leading to a dynamic equilibrium between four and three-coordinate specie. Its catalytic potential was tested in synthesis of propargylamines and 1,2,3-triazoles via three-component reactions. Experimental results discussed on base to DFT calculations.

Funding

Centro de Química, Instituto Venezolano de Investigaciones Cientifícas (IVIC)

History

Email Address of Submitting Author

juanmanuelgarfido@gmail.com

Institution

Universidad de Santiago de Chile, Departamento de Física, NanoSynthesis Laboratory

Country

Chile

ORCID For Submitting Author

0000-0003-4597-6149

Declaration of Conflict of Interest

The authors declare no conflict of interest.

Exports