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Nobel Metal Based High Entropy Alloy for Conversion of Carbon Dioxide (CO2) to Hydrocarbon

preprint
submitted on 06.09.2019 and posted on 09.09.2019 by Subramanian Nellaiappan, Nirmal Kumar, Ritesh Kumar, Arko Parui, Kirtiman Deo Malviya, K. G. Pradeep, Abhishek Kumar Singh, Sudhanshu Sharma, Chandra Sekhar Tiwary, Krishanu Biswas

Conversion of carbon-di-oxide into selective hydrocarbon using stable catalyst remains a holy-grail in catalysis community. The high overpotential, stability, and selectivity in use of a single metal-based catalyst still remain a challenge. In current work, instead of using pure noble metals (Ag, Au, and Pt) as the catalyst, a novel nanocrystalline high entropy alloy (HEA: AuAgPtPdCu) has been used for conversion of CO2 into gaseous hydrocarbons. Utilizing an approach of multi-metallic HEA, a Faradaic efficiency of about 100% towards gaseous products is obtained. The reason behind the superior catalytic activity of high entropy alloy (HEA) was established through first-principles based density functional theory (DFT) by comparing it with pristine Cu (111) surface. This is attributed to the reversal in adsorption trends for two out of the total eight intermediates - *OCH3 and *O on Cu(111) and HEA surfaces.

Funding

no funding

History

Email Address of Submitting Author

chandra.tiwary@metal.iitkgp.ac.in

Institution

Indian Institute of Technology Kharagpur

Country

India

ORCID For Submitting Author

0000-0001-9760-9768

Declaration of Conflict of Interest

no conflict of interest

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