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Ashuiev_et_al_Ti_nacnac-min.pdf (5.94 MB)

Molecular and Supported Ti(III)–Alkyls: Efficient Ethylene Polymerization Driven by π-Character of Metal-Carbon Bonds and Back Donation from a Singly Occupied Molecular Orbital

preprint
submitted on 24.07.2020 and posted on 24.07.2020 by Anton Ashuiev, Florian Allouche, Nino Wili, Keith Searles, Daniel Klose, Christophe Copéret, Gunnar Jeschke
Manuscript on a study on a homogeneous polymerization catalyst, its conversion to a heterogeneous catalyst by reaction with a support, an improvement of catalytic properties by this step, characterization of the structure of both catalysts, and insight into the mechanism of ethylene polymerization and its relation to electronic structure of intermediates.

All important information for interpreting and reproducing the findings is contained in the main text and the supplementary information appended within the same PDF document.

Funding

SNF-ANR grant MR-CAT 2-77275-15

History

Email Address of Submitting Author

gjeschke@ethz.ch

Institution

ETH Zürich

Country

Switzerland

ORCID For Submitting Author

0000-0001-6853-8585

Declaration of Conflict of Interest

No conflicts of interest

Version Notes

version 1.0, 24.7.2020

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