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Mild Temperature Copper-Catalyzed Amination of Aryl Halides with Aqueous Ammonia in the Presence of Pyridyldiketone Ligands

preprint
revised on 25.02.2019 and posted on 25.02.2019 by Racha Abed Ali Abdine, Anna Walczak, Sultan Abu A Aeash, Gracjan Kurpik, Artur R. Stefankiewicz, Florian Monnier, Marc Taillefer
Ambidentate ligand pyridyldiketones were used in combination with copper to catalyze amination of aryl halides under very mild temperatures with aqueous ammonia. This novel catalytic system allow efficient coupling in one of the smoothest conditions ever reported in literature.

Funding

National Science Centre in Poland grant UMO-2016/21/N/ST5/00851

National Centre for Research and Development grant LIDER/024/391/L-5/13/NCBR/2014)

CNRS

IUF

History

Email Address of Submitting Author

florian.monnier@enscm.fr

Institution

ENSCM Institut Charles Gerhardt Montpellier UMR 5253 CNRS

Country

France

ORCID For Submitting Author

0000-0002-9924-2012

Declaration of Conflict of Interest

no conflict of interest

Exports