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Mechanosynthesis of Sydnone-­Containing Coordination Complexes

preprint
revised on 18.06.2019 and posted on 19.06.2019 by Nicolas Petry, Thibaut Vanderbeeken, Astrid Malher, Yoan Bringer, Pascal Retailleau, Xavier Bantreil, Frédéric Lamaty

N-Phenyl-4-(2-pyridinyl) sydnone was shown to act as a four-electron donor N,O-ligand in unprecedented coordination complexes featuring four different metallic centers (Co, Cu, Zn). Starting from various anilines, the use of ball-mill enabled efficiently the synthesis of N-arylglycines, subsequent nitrosylation and cyclization into sydnone, and further metalation.

Funding

CNRS

University of Montpellier

Agence Nationale pour la Recherche/ANR-­10-­LABX-­05-­01

History

Email Address of Submitting Author

frederic.lamaty@umontpellier.fr

Institution

CNRS, Université de Montpellier

Country

France

ORCID For Submitting Author

0000-0003-2213-9276

Declaration of Conflict of Interest

Authors declare no conflict of interest

Version Notes

Version 1.0

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