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Mechanistic Investigations of an α-Aminoarylation Photoredox Reaction

preprint
submitted on 14.06.2020 and posted on 16.06.2020 by Bernard Stevenson, Ethan Spielvogel, Emily Loiaconi, Victor M. Wambua, Roman Nakhamiyayev, John SWIERK
We present time-dependent percent and quantum yield measurements of a photoredox-catalyzed coupling reaction between 1,4-dicyanobenzene and N-phenylpyrrolidine. We also use transient absorption spectroscopy to examine the kinetics within the reaction and use kinetic modeling to extract rate constants and predict how changes in rate constant will impact the quantum yield.

History

Email Address of Submitting Author

jswierk@binghamton.edu

Institution

Binghamton University (SUNY)

Country

United States

ORCID For Submitting Author

0000-0001-5811-7285

Declaration of Conflict of Interest

No conflict of interest

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