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Mechanistic Investigations Towards a Successful PET with Breslow-Intermediates
preprintrevised on 21.03.2021, 18:36 and posted on 23.03.2021, 08:43 by Jenny Phan, Julia Rehbein
Experimental mechanistic studies to learn about suitable conditions for a successful photocatalytic oxidation of Breslow intermediates.
a) address the effect of additives (oxidative, reductive) and assembly effects on PET and the dark reaction,
b) include the experimental support of a SET + HAT sequence directly connecting the primary adduct of aldhyde and NHC and the Breslow intermediate.