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Mechanistic investigations towards a successful PET with Breslow-Intermediates_Rehbein_upload.pdf (2.99 MB)

Mechanistic Investigations Towards a Successful PET with Breslow-Intermediates

preprint
submitted on 19.02.2021, 13:41 and posted on 22.02.2021, 06:50 by Jenny Phan, Julia Rehbein
Experimental mechanistic studies to learn about suitable conditions for a successful photocatalytic oxidation of Breslow intermediates.
Key findings
a) address the effect of additives (oxidative, reductive) and assembly effects on PET and the dark reaction,
b) include the experimental support of a SET + HAT sequence directly connecting the primary adduct of aldhyde and NHC and the Breslow intermediate.

Funding

Supported by the DFG via an Emmy-Noether stipend RE3630/1

History

Email Address of Submitting Author

julia.rehbein@ur.de

Institution

University Regensburg

Country

Deutschland

ORCID For Submitting Author

0000-0001-9241-0637

Declaration of Conflict of Interest

There is no conflict of interest.

Version Notes

first version

Exports

ChemRxiv

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