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Mechanistic Investigations Towards a Successful PET with Breslow-Intermediates
preprintsubmitted on 19.02.2021, 13:41 and posted on 22.02.2021, 06:50 by Jenny Phan, Julia Rehbein
Experimental mechanistic studies to learn about suitable conditions for a successful photocatalytic oxidation of Breslow intermediates.
a) address the effect of additives (oxidative, reductive) and assembly effects on PET and the dark reaction,
b) include the experimental support of a SET + HAT sequence directly connecting the primary adduct of aldhyde and NHC and the Breslow intermediate.