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Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling with Racemic Allyl Halides

preprint
revised on 29.01.2020 and posted on 29.01.2020 by Lucy van Dijk, Ruchuta Ardkhean, Mireia Sidera, Sedef Karabiyikoglu, Özlem Sari, Timothy D. W. Claridge, Robert Paton, Stephen P. Fletcher
A mechanism for Rh(I)-catalyzed asymmetric Suzuki-Miyaura coupling with racemic allyl halides is proposed based on a combination of experimental studies and quantum chemical calculations.

Funding

EP/N022246/1

EP/L015838/1

EP/L015722/1

ACI-1532235

ACI-1532236

History

Email Address of Submitting Author

lucy.vandijk@chem.ox.ac.uk

Institution

Oxford University

Country

United Kingdom

ORCID For Submitting Author

0000-0002-1899-087X

Declaration of Conflict of Interest

Oxford University Innovation has filed a patent application (PCT/GB2016/051612) with S.P.F. and M.S. named as inventors. The remaining authors declare no competing financial interests.

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