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Mechanistic Investigation of Rh(I)-Catalyzed Asymmetric Suzuki-Miyaura Coupling with Racemic Allyl Halides

preprint
revised on 29.01.2020, 11:45 and posted on 29.01.2020, 12:12 by Lucy van Dijk, Ruchuta Ardkhean, Mireia Sidera, Sedef Karabiyikoglu, Özlem Sari, Timothy D. W. Claridge, Robert Paton, Stephen P. Fletcher
A mechanism for Rh(I)-catalyzed asymmetric Suzuki-Miyaura coupling with racemic allyl halides is proposed based on a combination of experimental studies and quantum chemical calculations.

Funding

EP/N022246/1

EP/L015838/1

EP/L015722/1

ACI-1532235

ACI-1532236

History

Email Address of Submitting Author

lucy.vandijk@chem.ox.ac.uk

Institution

Oxford University

Country

United Kingdom

ORCID For Submitting Author

0000-0002-1899-087X

Declaration of Conflict of Interest

Oxford University Innovation has filed a patent application (PCT/GB2016/051612) with S.P.F. and M.S. named as inventors. The remaining authors declare no competing financial interests.

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