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Manganese Catalyzed Anti-Markovnikov Hydroamination of Allyl Alcohols via Hydrogen Borrowing Catalysis

preprint
submitted on 15.03.2021, 15:27 and posted on 16.03.2021, 12:44 by Kuhali Das, Koushik Sarkar, Biplab Maji
A phosphine ligand free manganese(I)-complex catalyzed the selective anti-Markovnikov hydroamination of allylic alcohols via waste-free hydrogen transfer mechanism. The γ-amino alcohol products are versatile synthetic intermediates for the synthesis of several drug molecules.

Funding

DST SERB (grant no. CRG/2019/001232)

History

Email Address of Submitting Author

bm@iiserkol.ac.in

Institution

Indian Institute of Science Education and Research Kolkata

Country

India

ORCID For Submitting Author

0000-0001-5034- 423X

Declaration of Conflict of Interest

The authors declare no conflict of interest.

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