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Stabilities of Siloxy Carbenes and Corresponding Oxocarbenium Ions.pdf (1.04 MB)
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Investigations into the Stability of Siloxy Carbene Intermediates and the Corresponding Oxocarbenium Ions

preprint
submitted on 18.06.2019 and posted on 18.06.2019 by Daniel Priebbenow
This report describes an investigation using dispersion-corrected DFT into the structures and stabilities of siloxy carbenes. Siloxy carbenes can be formed photochemically via a 1,2-Brook rearrangement and are an intriguing functional group that has exhibited diverse reactivity in organic synthesis. This investigation sheds light onto the key factors that influence the stability and reactivity of these carbene intermediates.

History

Email Address of Submitting Author

d.priebbenow@deakin.edu.au

Institution

Deakin University

Country

Australia

ORCID For Submitting Author

0000-0002-7840-0405

Declaration of Conflict of Interest

No conflict of interest

Version Notes

This is version1

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