ChemRxiv
These are preliminary reports that have not been peer-reviewed. They should not be regarded as conclusive, guide clinical practice/health-related behavior, or be reported in news media as established information. For more information, please see our FAQs.
1/1
0/0

Intermolecular Aminoallylation of Alkenes Using Allyl-Oxyphthalimide Derivatives: A Case Study in Radical Polarity Effects

preprint
submitted on 04.07.2019 and posted on 05.07.2019 by Samuel Lardy, Valerie Schmidt

A case study on the polarity effects of radical mediated intermolecular alkene aminoallylation is presented herein. This radical group transfer method pairs vinyl ethers with electronically deficient allyl-oxyphthalimide derivatives to give difunctionalized products while illustrating the guiding effects of polarity on this radical reactivity.

Funding

University of California San Diego start-up funds

History

Email Address of Submitting Author

vschmidt@ucsd.edu

Institution

University of California San Diego

Country

USA

ORCID For Submitting Author

0000-0001-9647-6756

Declaration of Conflict of Interest

The authors declare no competing financial interest

Exports

Logo branding

Exports