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Imidazole Promoted Efficient Anomerization of β-D-Glucose Pentaacetate in Organic Solutions and Solid State

preprint
revised on 11.02.2019 and posted on 11.02.2019 by Meifeng Wang, Liyin Zhang, Yiqun Li, Liuqun Gu

Anomerization of glycosides were rarely performed under basic condition due to lack of efficiency. Here an imidazole promoted anomerization of β-D-glucose pentaacetate was developed; and reaction could proceed in both organic solvents and solid state at room temperature. Although mechanism is not yet clear, this unprecedent mild anomerization in solid state may open a new promising way for stereoseletive anomerization of broad glucosides and materials design in the future..

Funding

Jinan University

History

Email Address of Submitting Author

guliuqun@yahoo.com

Institution

Jinan University

Country

China

ORCID For Submitting Author

0000-0002-4254-6824

Declaration of Conflict of Interest

no conflict of interest

Version Notes

Second vision with significant enriched by adding new finding of solid state reaction.

Exports