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Green Hydrosilylation of Olefins

preprint
submitted on 14.08.2018 and posted on 15.08.2018 by Valerica Pandarus,, Rosaria Ciriminna, Geneviève Gingras, François Béland, Serge Kaliaguine, Mario Pagliaro
Silicone precursors of high purity can now be synthesized via the solvent-free hydrosilylation of olefins mediated by highly stable and active hybrid glassy catalyst comprised of mesoporous organosilica microspheres doped with Pt nanoparticles. These findings open the route to more sustainable silicone manufacturing while providing desirable further reduction in the amount of platinum in silicones, namely ubiquitous advanced polymers with multiple uses and applications.

History

Email Address of Submitting Author

mario.pagliaro@cnr.it

Institution

CNR

Country

Italy

ORCID For Submitting Author

0000-0002-5096-329X

Declaration of Conflict of Interest

None

Exports