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Geometries and Terahertz Motions Driving Quintet Multiexcitons and Ultimate Triplet-Triplet Dissociations via the Intramolecular Singlet-Fissions

submitted on 05.08.2020, 13:01 and posted on 07.08.2020, 21:15 by Yasuhiro Kobori, Masaaki Fuki, Shunta Nakamura, Taku Hasobe
Importance of vibronic effects has been highlighted for the singlet-fission (SF) that convert one high-energy singlet exciton into doubled triplet excitons, as strongly correlated multiexcitons. However, molecular mechanisms of spin conversion processes and ultimate de-couplings in the multiexcitons are poorly understood. We have analyzed geometries and exchange couplings of the photoinduced multiexcitons in the pentacene dimers bridged by a phenylene at ortho and meta positions [denoted as o-(Pc)2 and m-(Pc)2] by simulations of the time-resolved electron paramagnetic resonance spectra. We clarified that terahertz molecular conformation dynamics plays a role on the spin conversion from the singlet strongly coupled multiexcitons 1(TT) to the quintet state 5(TT). The strongly coupled 5(TT) multiexcitons are revealed to possess entirely planar conformations stabilized by mutually delocalized spin distributions, while the intramolecular de-coupled spin-correlated triplet pairs generated at 1 microsecond are also stabilized by distorted conformations resulting in two separately localized biradical characters.





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Kobe University



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Declaration of Conflict of Interest

The authors declare no competing financial interests.