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Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands

preprint
submitted on 25.06.2018 and posted on 26.06.2018 by Kent O. Kirlikovali, Jonathan C. Axtell, Kierstyn Anderson, Peter I. Djurovich, Arnold L. Rheingold, Alexander Spokoyny
We report the synthesis of two isomeric Pt(II) complexes ligated by doubly deprotonated 1,1′-bis(o-carborane) (bc). This work provides a potential route to fine-tune the electronic properties of luminescent metal complexes by virtue of vertex-differentiated coordination chemistry of carborane-based ligands.

History

Email Address of Submitting Author

spokoyny@chem.ucla.edu

Institution

University of California, Los Angeles

Country

USA

ORCID For Submitting Author

0000-0002-5683-6240

Declaration of Conflict of Interest

No conflicts of interest are associated with this submission.

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