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Maintext and SI- Experimental and computational evidence of non-MEP Pathways.pdf (9.56 MB)

Experimental and Computational Evidence of non-MEP Pathways in the Fragmentation and Rearrangement of Bicyclo[3.3.1] heptane Diazonium Ions

preprint
submitted on 23.02.2021, 09:34 and posted on 24.02.2021, 11:14 by Bastian Wulff, Patrick Sakrausky, Katrin Adamczyk, Nils Huse, Julia Rehbein
The non-minimum energy pathways on the fragmentation of bicyclic diazoniumions and subsequent carbocationic rearrangements has been studied by a combination of computational chemistry (MD simulations, IRC, stationary point analysis) and experiments (TR-IR and UV from ps to µs, NMR kinetics).

Funding

DFG funded via an Emmy-Noether stipend RE3630/1

History

Email Address of Submitting Author

juliarehbein@ur.de

Institution

University Regensburg

Country

Deutschland

ORCID For Submitting Author

0000-0001-9241-0637

Declaration of Conflict of Interest

No conflict of interest to be declared.

Version Notes

Version 1 uploaded

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