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Electronic Structure Modulation in Cationic Boron Formazanate Complexes
preprintsubmitted on 20.10.2020, 16:02 and posted on 21.10.2020, 09:07 by Ryan Maar, Benjamin D. Katzman, Paul D. Boyle, Viktor N. Staroverov, Joe Gilroy
The effect of charge, coordination number, and supporting ligands at boron in formazanate-based BN heterocycles is systematically explored. It is shown that the type and wavelength of the lowest-energy electronic excitation of these compounds can be modulated through structural variation at boron.