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Electronic Structure Modulation in Cationic Boron Formazanate Complexes

preprint
submitted on 20.10.2020, 16:02 and posted on 21.10.2020, 09:07 by Ryan Maar, Benjamin D. Katzman, Paul D. Boyle, Viktor N. Staroverov, Joe Gilroy
The effect of charge, coordination number, and supporting ligands at boron in formazanate-based BN heterocycles is systematically explored. It is shown that the type and wavelength of the lowest-energy electronic excitation of these compounds can be modulated through structural variation at boron.

Funding

NSERC of Canada

Canadian Foundation for Innovation

Ontario Ministry of Research and Innovation

History

Email Address of Submitting Author

joe.gilroy@uwo.ca

Institution

The University of Western Ontario

Country

Canada

ORCID For Submitting Author

https://orcid.org/0000-0003-0349-7780

Declaration of Conflict of Interest

No conflict of interest.

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