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Electronic Band Contraction Induced Low Temperature Methane Activation on Metal Alloys

preprint
submitted on 14.12.2019 and posted on 20.12.2019 by Victor Fung, Guoxiang Hu, Bobby Sumpter
The catalytic conversion of methane under mild conditions is an appealing approach to selectively produce value-added products from natural gas. Catalysts which can chemisorb methane can potentially overcome challenges associated with its high stability and achieve facile activation. Although transition metals can activate C-H bonds, chemisorption and low-temperature conversion remains elusive on these surfaces. The broad electronic bands of metals can only weakly interact with the methane orbitals, in contrast to specific transition metal oxide and supported metal cluster surfaces which are now recognized to form methane σ-complexes. Here, we report methane chemisorption can, remarkably, occur on metal surfaces via electronic band contraction and localization from metal alloying. From a broad screening including single atom and intermetallic alloys in various substrates, we find early transition metals as promising metal solutes for methane chemisorption as well as low-temperature activation. These findings demonstrate a combinatorial diversity of possible candidates in earth abundant metal alloys with this attractive catalytic behavior.

History

Email Address of Submitting Author

fungv@ornl.gov

Institution

Oak Ridge National Laboratory

Country

United States

ORCID For Submitting Author

0000-0002-3347-6983

Declaration of Conflict of Interest

No conflicts of interest

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