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Direct Measurement of the Visible to UV Photodissociation Processes for the PhotoCORM TryptoCORM

preprint
submitted on 15.12.2019 and posted on 23.12.2019 by Rosaria Cercola, Kaitlyn Fischer, Summer Scherman, etienne garand, Natalie Wong, Anders Hammarback, Jason Lynam, Ian Fairlamb, Caroline E. H. Dessent
We apply laser photodissociation spectroscopy in the gas phase to TryptoCORM, a known photoCORM that has been shown to destroy Escherichia coli upon visible-light activation. Our experiments allow us to fully map TryptoCORM’s photochemistry across a wide wavelength range by using novel laser-interfaced mass spectrometry (LIMS). We complement these measurements with Cryogenic Ion Vibrational Spectroscopy (CIVS), to structurally characterise gaseous TryptoCORM.

Funding

CHE-1454086

History

Email Address of Submitting Author

caroline.dessent@york.ac.uk

Institution

University of York

Country

UK

ORCID For Submitting Author

0000-0003-4944-0413

Declaration of Conflict of Interest

No conflict of interest

Version Notes

Version 1 (First uploaded version 15/12/2019)

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