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Direct Access to (±)-10-Desbromoarborescidine A from Tryptamine and Pentan-1,5-diol

preprint
submitted on 09.12.2019 and posted on 17.12.2019 by Apurba Ranjan Sahoo, Gummidi Lalitha, V. Murugesh, Christian Bruneau, Gangavaram V. M. Sharma, Surisetti Suresh, Mathieu Achard
A single step synthetic strategy for (±)10- Desbromoarborescidine A is described. Starting from tryptamine and pentan-1,5-diol, this acceptorless dehydrogenative condensation process is efficiently catalyzed by a ruthenium complex featuring proton-responsive phosphine pyridone ligand.
Manuscript is available supporting material is available and includes experimental procedures, characterization of compounds, 1H, 13C NMR spectra and chromatograms.

Funding

CEFIPRA/IFCPAR No. 5105-4

History

Email Address of Submitting Author

mathieu.achard@univ-rennes1.fr

Institution

université de Rennes 1

Country

France

ORCID For Submitting Author

0000-0003-0578-9680

Declaration of Conflict of Interest

no conflict of interest

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