Direct Access to (±)-10-Desbromoarborescidine A from Tryptamine and Pentan-1,5-diol

Apurba Ranjan Sahoo; Gummidi Lalitha; V. Murugesh; Christian Bruneau; Gangavaram V. M. Sharma; Surisetti Suresh; Mathieu Achard

doi:10.26434/chemrxiv.11341379.v1

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Direct Access to (±)-10-Desbromoarborescidine A from Tryptamine and Pentan-1,5-diol

17 December 2019, Version 1

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Abstract

A single step synthetic strategy for (±)10- Desbromoarborescidine A is described. Starting from tryptamine and pentan-1,5-diol, this acceptorless dehydrogenative condensation process is efficiently catalyzed by a ruthenium complex featuring proton-responsive phosphine pyridone ligand.

Manuscript is available supporting material is available and includes experimental procedures, characterization of compounds, 1H, 13C NMR spectra and chromatograms.

Keywords

indoloquinolizine

Green Chemistry Approach

Natural products

Homogeneous Catalysis

hydrogen transfer

Supplementary materials

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Supporting Information Desbromoarborescidine Modified Apurba 2019 12 09

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Now Published

Direct Access to (±)‐10‐Desbromoarborescidine A from Tryptamine and Pentane‐1,5‐diol

Apurba Ranjan Sahoo, Gummidi Lalitha, V. Murugesh, Christian Bruneau, Gangavaram V. M. Sharma, Surisetti Suresh, Mathieu Achard journal article

Asian Journal of Organic Chemistry , Volume 9, Issue 6

Online publication date: May 05, 2020

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Dec 17, 2019 Version 1

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The content is available under CC BY NC ND 4.0

DOI

10.26434/chemrxiv.11341379.v1

Funding

CEFIPRA/IFCPAR No. 5105-4

Author’s competing interest statement

no conflict of interest

Direct Access to (±)-10-Desbromoarborescidine A from Tryptamine and Pentan-1,5-diol

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Abstract

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Supplementary materials

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