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Dibenzo-Tetraphenyl Diindeno as Hole Transport Layer for Perovskite Solar Cells Fabrication

preprint
submitted on 06.03.2020 and posted on 09.03.2020 by Meenakshi Pegu, Laura Calio, Mehrad Ahmadpour, Horst-Günter Rubahn, Samrana Kazim, Morten Madsen, Shahzada Ahmad

Semi-transparent perovskite solar cells have the competitive edge of being employed for building integrated photovoltaics due to their aesthetic benefits as light harvesting windows / facades. Perovskites have received considerable attention in recent years as a thin film photovoltaic alternative, that can also be tweaked for its transparency, evolving from potentially high bandgaps that are suited for semi-transparent solar cell fabrication. Due to the existing trade of between the efficiency and transparency of a perovskite solar cell, tuning the band gap can address this by making a bridge between the aforementioned parameters. We report our findings on the use of a wide-bandgap perovskite MAPbBr3, with a rational energetic level hole transport materials based on polycyclic aromatic hydrocarbon molecules that can be a promising alternative class of p-type material. In the present work, DBP (Dibenzo{[f,f' ]-4,4',7,7'-tetraphenyl}diindeno[1,2,3-cd :1',2',3'-lm]perylene, was evaluated with high band gap as well as with (FAPbI3)0.85(MAPbBr3)0.15 perovskites for the fabrication of solar cell. DBP based solar cells yielded competitive power conversion efficiencies as compared to classical HTMs.

Funding

EU H2020 Excellence

FP7

History

Email Address of Submitting Author

shahzada.ahmad@bcmaterials.net

Institution

BCMaterials-Basque center for materials, applications & nanostructures

Country

Spain

ORCID For Submitting Author

0000-0002-1218-2556

Declaration of Conflict of Interest

no conflict of interest to declare

Version Notes

Submitted version

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