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Detection of Adsorbates on Emissive MOF Surfaces with X-Ray Photoelectron Spectroscopy
preprintsubmitted on 16.10.2018, 03:23 and posted on 16.10.2018, 13:38 by Shawn Burdette, Jingjing Yan, Ron Grimm, Peter Mueller, Alexander Carl, John MacDonald
A metal organic framework containing an azobenzene chromophore exhibits luminescence that is quenched by nitro-phenol derivatives. The model system was used to develop an new analytical approach to differentiating between encapsulated guest molecules and those adsorbed on the outside of the MOF