Cross-Coupling Polymerization at Iodophenyl Thin Films Prepared by Spontaneous Grafting of a Diazonium Salt

17 February 2020, Version 2
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Development of a method for the surface-initiated Kumada cross-coupling polymerization based on 4-iodophenyldiazonium salt thin films. Studies of the kinetics of chain termination and polymer film growth, and use of this method to make polythiophene brushes.

Keywords

cross-coupling
KCTP
surface-initiated polymerization
diazonium
thin film
polythiophene
conjugated polymer

Supplementary materials

Title
Description
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Title
Marshall PeerJ Materials Science 2019 SI Revision 1
Description
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