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Cr(II) and Cr(I) PCP Pincer Complexes: Synthesis, Structure, and Catalytic Reactivity

preprint
submitted on 01.11.2019, 08:17 and posted on 07.11.2019, 21:39 by Daniel Himmelbauer, Berthold Stöger, Luis F. Veiros, Marc Pignitter, Karl Kirchner

We report the synthesis of the square-planar Cr(II) PCP complex [Cr(POCOP-tBu)(Br)] which is a valuable precursor for novel chromium borohydride PCP pincer complexes in formal oxidation states +I and +II.

Funding

Austrian Science Fund P29584-N28

History

Email Address of Submitting Author

karl.kirchner@tuwien.ac.at

Institution

Technical University Vienna

Country

Austria

ORCID For Submitting Author

0000-0003-0872-6159

Declaration of Conflict of Interest

There are is no conflict of interest

Version Notes

Version 1.0

Exports