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Correlation between Yield and Reduced Massof Raw Materials in Intermolecular and Intramolecular Cyclization Reactions.pdf (601.51 kB)

Correlation between Yield and Reduced Mass of Raw Materials in Intermolecular and Intramolecular Cyclization Reactions

preprint
submitted on 09.12.2020, 02:24 and posted on 10.12.2020, 05:33 by Masatoshi Kawashima
Correlation between yield and reduced mass of raw materials in intramolecular C-N, C-C, C-O coupling reactions and intramolecular/intermolecular Diels-Alder reactions was revealed. The regression equation was found to be the same as that of intermolecular reactions; yield = -0.1861MAB/(nAnBnI)+100.0, where MAB is the reduced mass per mole and nA and nB are the total number of each reaction site in molecular A and molecular B in the reaction system, and nI is the number to distinguish whether it is a intramolecular reaction or intermolecular reaction.

History

Email Address of Submitting Author

kawashima@azuma-g.co.jp

Institution

Azuma Co., Ltd.

Country

Japan

ORCID For Submitting Author

0000-0002-1849-2053

Declaration of Conflict of Interest

No conflict of interest

Version Notes

20201209-1

Exports

ChemRxiv

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