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Concise Synthesis of Complex Taxane Diterpene Canataxpropellane by Photochemical Dearomatization
preprintsubmitted on 02.08.2019, 16:38 and posted on 05.08.2019, 15:17 by Fabian Schneider, Konstantin Samarin, Simone Zanella, Tanja Gaich
Our work describes the first total synthesis of a complex taxane canataxpropellane. The synthesis is based on a photechemicalr eaction - a orthodoxy-alkene-arene-photocycloaddion. The route is concise providing material for biological testing