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Transition between [R]- and [S]-Stereoisomers without Bond Breaking

preprint
revised on 30.05.2020 and posted on 01.06.2020 by Shampa Raghunathan, Komal Yadav, V. C. Rojisha, Tanashree Jaganade, V. Prathyusha, Swetha Bikkina, Upakarasamy Lourderaj, U. Deva Priyakumar
We for the first time shown that transition between (R) and (S) stereoisomers via a planar transition state or an intermediate structure without having to break a bond is possible. Rigorous theoretical calculations have been used to study this novel phenomenon and to characterize the energetic, structure, dynamic and kinetic properties.

Funding

DST-SERB (Grant No. EMR/2016/007697)

DST-SERB (Grant No. PDF/2018/000142)

History

Email Address of Submitting Author

deva@iiit.ac.in

Institution

International Institute of Information Technology

Country

India

ORCID For Submitting Author

0000-0001-7114-3955

Declaration of Conflict of Interest

There is no conflict of interest.

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