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Cavity catalysis by co-operative VSC.pdf (521.61 kB)

Cavity Catalysis by Co-operative Vibrational Strong Coupling of Reactant and Solvent Molecules

submitted on 29.12.2018, 13:43 and posted on 31.12.2018, 15:42 by Jyoti Lather, Pooja Bhatt, Anoop Thomas, Thomas W. Ebbesen, Jino George
para-nitrophenyl acetate hydrolysis is studied under vibrational strong coupling in a Fabry-Perot cavity. By tuning the cavity resonance to the C=O vibrational stretching mode of both the reactant and solvent molecules, it is found that the reaction is accelerated by an order of magnitude. It is shown that this cavity catalysis involves a co-operative strong coupling effect between the solvent and reactant molecules. The reaction rate follows an exponential relation with respect to the solvent coupling strength. The combination of co-operative effects and cavity catalysis confirms the potential of VSC as a new frontier in chemistry.


DST-SERB, Core Research Grant (EMR/2017/003455)


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Indian Institute of Science Education and Research (IISER) Mohali



ORCID For Submitting Author


Declaration of Conflict of Interest