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Boosting Fast and Stable Potassium-ion Storage by Synergistic Interlayer and Pore-structure Engineering

preprint
submitted on 29.05.2020 and posted on 01.06.2020 by Deping Li, Qing Sun, Yamin Zhang, Xinyue Dai, Fengjun Ji, kaikai Li, Qunhui Yuan, Xingjun Liu, Lijie Ci

Carbon-based material has been regarded as one of the most promising electrode materials for Potassium-ion batteries (PIBs). However, the battery performance based on reported porous carbon electrodes is still unsatisfactory, while the in-depth K-ion storage mechanism remains relatively ambiguous. Herein, we propose a facile “in situ template bubbling” method for synthesizing interlayer tuned hierarchically porous carbon with different metallic ions, which delivers superior K-ion storage performance, especially the rate capability (158.6 mAh g-1@10.0 A g-1) and high-rate cycling stability (82.8% capacity retention after 2000 cycles at 5.0 A g-1). The origin of the excellent rate performance is revealed by the deliberately designed consecutive CV measurements, Ex situ Raman tests, GITT and theoretical simulations. Considering the facile preparation strategy, superior electrochemical performance and insightful mechanism investigations, this work can provide fundamental understandings for high performance PIBs and related energy storage devices like sodium-ion batteries, aluminum-ion batteries, electrochemical capacitors and dual-ion batteries.

Funding

High-level Talents' Discipline Construction Fund of Shandong University(Grant No. 31370089963078)

School Research Startup Expenses of Harbin Institute of Technology (Shenzhen) (Grant No. DD29100027)

China Postdoctoral Science Foundation (Grant No. 2019M661276)

Guangdong Basic and Applied Basic Research Foundation (Grant No. 2019A1515110756)

History

Email Address of Submitting Author

lideping@hit.edu.cn

Institution

Harbin Institute of Technology (Shenzhen)

Country

China

ORCID For Submitting Author

0000-0002-2116-5184

Declaration of Conflict of Interest

No

Version Notes

Completed version 1

Exports