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Bond-length distributions for ions bonded to oxygen: Results for the lanthanides and actinides and discussion of the f-block contraction

preprint
revised on 05.12.2017 and posted on 05.12.2017 by Olivier Charles Gagné
Bond-length distributions have been examined for eighty-four configurations of the lanthanide ions and twenty-two configurations of the actinide ions bonded to oxygen. The lanthanide contraction for the trivalent lanthanide ions bonded to O2- is shown to vary as a function of coordination number and to diminish in scale with increasing coordination number.

Funding

NSERC; University of Manitoba

History

Topic

  • Solid State Chemistry

Email Address of Submitting Author

umgagneo@myumanitoba.ca

Institution

University of Manitoba

Country

Canada

ORCID For Submitting Author

0000-0002-7902-8166

Declaration of Conflict of Interest

No conflict of interest.

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Read the published paper

in Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials

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