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Bismuthanylstibanes

preprint
revised on 09.01.2020 and posted on 09.01.2020 by Katherine Marczenko, Saurabh Chitnis
Thermally-robust bismuthanylstibanes are prepared in a one-step, high yield reaction, providing the first examples of neutral Bi–Sb σ-bonds in the solid state. DFT calculations indicate that the bis(silylamino)naphthalene scaffold is well-suited for supporting otherwise labile bonds. The reaction chemistry of the Bi–Sb bond is exploited by showing insertion of a sulfur atom, providing the first documented example of a Bi–S–Sb bonding moiety.

History

Email Address of Submitting Author

saurabh.chitnis@dal.ca

Institution

Dalhousie University

Country

Canada

ORCID For Submitting Author

0000-0001-9180-7907

Declaration of Conflict of Interest

None

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