ChemRxiv
These are preliminary reports that have not been peer-reviewed. They should not be regarded as conclusive, guide clinical practice/health-related behavior, or be reported in news media as established information. For more information, please see our FAQs.
KubanMOF5manuscript_InorgChem_overbarfixed_20180816.pdf (642.17 kB)

Basic Zinc Cubane-1,4-Dicarboxylate: A New MOF-5 Analogous with High Porosity and Robust Dynamics

preprint
submitted on 14.02.2020, 10:01 and posted on 17.02.2020, 05:56 by Dávid Földes, Éva Kováts, Gábor Bortel, Szilvia Klébert, Emma Jakab, Sándor Pekker
A new metal-organic framework, basic zinc cubane-1,4-dicarboxylate, (1) was synthesized. 1 is a cubic framework of the same underlying topology, as basic zinc terephthalate, MOF-5, with similar lattice parameters, unique dynamics and competitive adsorption properties. It has a highsymmetry space group, Pm3,¯m with a lattice parameter of 12.776 Å, as determined by X-ray diffraction at 100 K. The structure consists of a random distribution of two perpendicular basic zinc carboxylate nodes and axially disordered cubylene spacers, so the observed high-symmetry structure is an average of several lower-symmetry unit cells. The binary orientational disorder of the nodes has significant influence on the uniaxial rotation of the edges, realizing a previous idea of robust dynamics1. The structural and dynamical ifferences of 1 and MOF-5 are based on the local symmetry and the electronic structure of the organic components: i) the lack of conjugation in cubane-1,4-dicarboxylate does not fix the orientation of the nodes; and ii) the incomplete match of the cubylene (rotor) and dicarboxylate (stator) units facilitates the rotation of the cubylene units even at 100 K. The calculated rotation barrier is unusually low, and it depends on the orientation of the adjacent carboxylate units. The crystals of 1 can be activated either at elevated temperature in vacuum or at ambient conditions by solvent exchange. The high surface area (3160 m2g-1) and the high capacity of hydrogen uptake promise future practical applications.

History

Email Address of Submitting Author

kovats.eva@wigner.mta.hu

Institution

Institute for Solid State Physics and Optics, Wigner Research Centre for Physics

Country

Hungary

ORCID For Submitting Author

0000-0002-8358-857X

Declaration of Conflict of Interest

No conflict of interest.

Version Notes

Submitted to Inorganic chemistry: 16.08.2018 Last version: 10.05.2019

Exports

Logo branding

Exports