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InterfacialWater.pdf (2.88 MB)

Anomalously High Proton Conduction of Interfacial Water

preprint
submitted on 18.01.2020, 10:22 and posted on 21.01.2020, 09:26 by Vasily Artemov, Ece Uykur, Pavel Kapralov, Alexei Kiselev, Keith Stevenson, Henni Ouerdane, Martin Dressel
Water at the solid-liquid interface exhibits an anomalous ionic conductivity and dielectric constant compared to bulk water. Both phenomena still lack a detailed understanding. Here, we report radiofrequency measurements and analyses of the electrodynamic properties of interfacial water confined in nano-porous matrices formed by diamond grains of various sizes, ranging from 5 nm to 0.5 μm in diameter. Contrary to bulk water, the charge-carrying protons/holes in interfacial water are not mutually screened allowing for higher mobility in the external electric field. Thus, the protonic conductivity reaches a maximum value, which can be five orders of magnitude higher than that of bulk water. Our results aid in the understanding of physical and chemical properties of water confined in porous materials, and pave the way to the development of new type of highly-efficient proton-conductive materials for applications in electrochemical energy systems, membrane separations science and nano-fluidics.

History

Email Address of Submitting Author

henni_ouerdane@hotmail.com

Institution

Skolkovo Institute of Science and Technology

Country

Russia

ORCID For Submitting Author

0000-0002-1914-0244

Declaration of Conflict of Interest

The authors declare no conflict of interests.

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