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AuGO Manuscript_2020 11 09_FINAL.pdf (2.28 MB)

Anchoring Carboxyl Functionalized Gold-Aryl Nanoparticles to Graphene Oxide Platforms for Environmental Nanoremediation

preprint
submitted on 09.11.2020, 21:08 and posted on 10.11.2020, 12:08 by Javad Parambath, Najrul Hussain, Mahreen Arooj, Maria Omastova, Mohamed Chehimi, Changseok Han, Ahmed A. Mohamed
Graphene oxide (GO) was decorated with gold-aryl (Au-C) nanoparticles AuNPs-COOH by sodium borohydride reduction of aryldiazonium tetrachloroaurate(III) salt at room temperature in aqueous solutions. BET (Brunauer-Emmett-Teller) measurements supported the anchoring of GO by AuNPs modified with carboxyl functional groups; surface area dropped significantly. Morphology of AuNPs-COOH/GO nanocomposite (NC) was probed using AFM and TEM and images showed surface roughness and wrinkling. Molecular dynamics (MD) calculations endowed support of favorable wrinkling at the edges and carboxyl intercalation to GO surface of types p-p, hydrogen bonding, and hydrophobic interactions. Solvent accessible surface area calculations (SASA) of GO showed a decrease in total surface area, in agreement with BET results. Environmental nanoremediation of the catalytic reduction of nitrophenol and the electrocatalytic reduction of CO2 (model pollutants) were investigated. The apparent rate constants Kapp of the four catalytic reduction cycles of nitrophenol were measured. The highest value is 1.17 × 10-1 min-1 for the first cycle which decreased to 4.49 × 10-2 min-1 for the fourth cycle. Electrocatalytic studies revealed that the NC enhanced the CO2 reduction. The NC exhibited higher current densities in the CO2 solution saturated (48 mA/cm2) compared to N2 (37 mA/cm2), indicating its superior catalytic activity in CO2 reduction.

Funding

VEGA 02/0010/18

VC-GRC-SR-83-2015

160-2142-029-P

150-2142-017-P

RISE-046-2016

151-0039

History

Email Address of Submitting Author

mmchehimi@yahoo.fr

Institution

CNRS

Country

France

ORCID For Submitting Author

0000-0002-6098-983X

Declaration of Conflict of Interest

The authors declare no conflict of interest

Version Notes

Version v1

Exports