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Aminoxyl-Catalyzed Electrochemical Diazidation of Alkenes

preprint
revised on 04.12.2018 and posted on 05.12.2018 by Juno C. Siu, Joseph B. Parry, Song Lin

We report the hypothesis-driven development of a new aminoxyl radical catalyst, CHAMPO, for the electrochemical diazidation of alkenes. Mediated by an anodically generated charge-transfer complex in the form of CHAMPO–N3, the radical diazidation was achieved across a broad scope of structurally diverse alkenes. Preliminary mechanistic data lend support for a dual catalytic role of the aminoxyl serving as both a single-electron oxidant and a radical group transfer agent.

Funding

NIH R01 GM130928

History

Email Address of Submitting Author

songlin@cornell.edu

Institution

Cornell University

Country

USA

ORCID For Submitting Author

0000-0002-8880-6476

Declaration of Conflict of Interest

No conflict of interest

Version Notes

Version one

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