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Aminobismuthination of CO2

preprint
revised on 22.01.2021, 14:07 and posted on 25.01.2021, 08:36 by Katherine Marczenko, Saurabh Chitnis
We report the facile (25 oC, 1 atm, <5 minutes) and selective insertion of CO2 into Bi-N bonds to yield bismuth carbamates. The role of ligand and substituent on promoting the controlled aminobismuthination of CO2 and rendering the bismuth carbamate products stable against thermal decomposition and ligand degradation is revealed.

History

Email Address of Submitting Author

saurabh.chitnis@dal.ca

Institution

Dalhousie University

Country

Canada

ORCID For Submitting Author

0000-0001-9180-7907

Declaration of Conflict of Interest

None

Version Notes

Version 2.0

Exports