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Aggregation-Induced Emission Luminogen: The New Perspective in Photo-Degradation of Organic Pollution

preprint
submitted on 18.07.2019, 05:23 and posted on 19.07.2019, 13:20 by Xing Feng, Ying Li, Zhen Hu, Qingsong Wang, mengsi chem, Haoke Zhang, Miaomiao Kang, zheng zhao, Md. Monarul Islam, Jun Zhang, Ye Xiao, Menglong Zhang, Carl Redshaw, Qing Chen, Sheng Xie, Jacky W. Y. Lam, Ben Zhong Tang

Both the variety and uniqueness of organic semiconductors has contributed to the rapid development of environmental engineering applications and renewable fuel production, typified by photo-degradation of organic pollutants or water splitting. This paper presents a rare example of an aggregation-induced emission luminogen (AIEgen) as a highly efficient photo-catalyst for pollutant decomposition in an environmentally relevant application. Under irradiation, the tetraphenylethene-based AIEgen (TPE-Ca) exhibited high photo-degradation efficiency of up to 98.7% of Rhodaminein (RhB) in aqueous solution. The possible photocatalytic mechanism was studied by electron paramagnetic resonance (EPR) and X-ray photoelectron spectroscopy (XPS) spectra, electrochemistry, thermal imaging technology, ultra-performance liquid chromatography and high-definition mass spectrometry (UPLC/HDMS), as well as by density functional theory (DFT) calculations. Cytotoxicity experiments indicated that the final photo-catalytic degradation products show biocompatibility. Among the many diverse AIEgens, this is the first AIEgen to be developed as a photo-catalyster of organic pollutants. This research will open up new avenues for AIEgens research, particularly for applications of environmental relevance.

History

Email Address of Submitting Author

hyxhn@sina.com

Institution

Guangdong University of Technology

Country

China

ORCID For Submitting Author

0000-0002-4273-979X

Declaration of Conflict of Interest

No Conflict of interest.

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