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Ag(I)/TiO2-Photocatalyzed N-Methylation of Amino Acids with Methanol

07 July 2020, Version 2
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Silver(I)-loaded titanium dioxide (AgNO3/TiO2) catalyzes the direct N-methylation of amino acids with methanol under irradiation with UV light. This method produces a variety of N-methyl and N,N-dimethyl amino acids with retention of their optical purity.

Keywords

N-methylation
Amino acid residues

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Version History

Jul 07, 2020 Version 2

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.12588266.v2
D O I: 10.26434/chemrxiv.12588266.v2 [opens in a new tab]

Funding

JSPS KAKENHI Grant Number JP26410115
JGC Scholarship Foundation
Iwatani Foundation
Fukuoka Naohiko Memorial Foundation

Author’s competing interest statement

No conflict of interest

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