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Absolute asymmetric catalysis gas phase.pdf (301.51 kB)

Absolute Autocatalytic Amplification Under Heterogenous Conditions Involving Subsequent Hydride Transfer and Hemiacetal Intermediate.

preprint
submitted on 14.08.2019 and posted on 15.08.2019 by Giuesppe rotunno, Dirk Petersen, Mohamed Amedjkouh
Absolute asymmetric amplification is observed for pyridine alkanol by reaction with iPr2Zn vapor under heterogenous conditions. Beside the chiral alkanol, formation of a chiral ester is observed and identified as a subsequent Claisen-Tishchenko product of a hemiacetal intermediate during a Soai absolute amplification.

History

Email Address of Submitting Author

mamou@kjmei.uio.no

Institution

University of Oslo

Country

Norway

ORCID For Submitting Author

0000-0002-2707-7767

Declaration of Conflict of Interest

No conflict of interest

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