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revised on 04.03.2020 and posted on 05.03.2020by James P. Fraser, Liudvika Masaityte, Jingyi Zhang, Stacey Laing, Juan Carlos Moreno-López, Adam McKenzie, Jessica McGlynn, Vishal Panchal, Duncan Graham, Olga Kazakova, Thomas Pichler, Donald A. MacLaren, David A.J. Moran, Alexey Y. Ganin
Minor structural changes in transition metal dichalcogenides can have dramatic effects on their electronic properties. This makes the quest for key parameters that can enable a selective choice between the competing metallic and semiconducting phases in the 2D MoTe2 system compelling. Herein, we report the optimal conditions at which the choice of the initial seed layer dictates the type of crystal structure of atomically-thin MoTe2 films grown by chemical vapour deposition (CVD). When Mo metal is used as a seed layer, phase-pure semiconducting 2H-MoTe2 is the only product. Conversely, MoO3 leads to the preferential growth of phase-pure metallic 1Tꞌ-MoTe2. The control over phase growth allows for simultaneous deposition of both 2H-MoTe2 and 1Tꞌ-MoTe2 phases on a single substrate during one CVD reaction. Furthermore, Rhodamine 6G dye can be detected using few-layered 1Tꞌ-MoTe2 films down to 5 nM concentration which is several orders of magnitude higher than the value observed for bulk 1Tꞌ-MoTe2.
We acknowledge the University of Glasgow, EPSRC (EP/P001653/1), and the Carnegie Trust for a Research Incentive Grant (RIG007428) for supporting this work. T.P. thanks the FWF P27769-N20 for funding. J.P.F thanks the Energy Technology Partnership for the PECRE grant awarded.