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A Triazole-Substituted Aryl Iodide with Omnipotent Reactivity in Enantioselective Oxidative Couplings

preprint
submitted on 29.08.2019 and posted on 30.08.2019 by Ayham Abazid, Boris Nachtsheim
A triazole-substituted chiral aryl iodide is described as an efficient catalyst for a variety of diverse oxidative coupling reactions such as the Kita-spirocyclization, phenol-dearomatizations, alpha-oxygenations and oxidative rearrangements. Structures of the in situ oxidized hydroxy(tosyloxy)iodoarenes are discussed based on DFT-calculations.

History

Email Address of Submitting Author

nachtsheim@uni-bremen.de

Institution

Universität Bremen

Country

Germany

ORCID For Submitting Author

0000-0002-3759-2770

Declaration of Conflict of Interest

no conflict of interest

Version Notes

first version

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