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A Triazole-Substituted Aryl Iodide with Omnipotent Reactivity in Enantioselective Oxidative Couplings
preprintsubmitted on 29.08.2019, 15:19 and posted on 30.08.2019, 15:11 by Ayham Abazid, Boris Nachtsheim
A triazole-substituted chiral aryl iodide is described as an efficient catalyst for a variety of diverse oxidative coupling reactions such as the Kita-spirocyclization, phenol-dearomatizations, alpha-oxygenations and oxidative rearrangements. Structures of the in situ oxidized hydroxy(tosyloxy)iodoarenes are discussed based on DFT-calculations.