ChemRxiv
These are preliminary reports that have not been peer-reviewed. They should not be regarded as conclusive, guide clinical practice/health-related behavior, or be reported in news media as established information. For more information, please see our FAQs.
1/1
2 files

A Photochemical Strategy for Carbon Isotope Exchange with CO2

preprint
submitted on 31.10.2020, 21:17 and posted on 02.11.2020, 12:00 by Victor Babin, Alex Talbot, Alexandre Labiche, Gianluca Destro, Antonio Del Vecchio, Charles S. Elmore, Frédéric Taran, Antoine Sallustrau, Davide Audisio
A novel photocatalytic approach for carbon isotope exchange is reported. Utilizing [13C]CO2 as primary C1 sources, this protocol allows the insertion of the desired carbon isotope into phenyl acetic acids without the need of structural modifications or pre-functionalization, in one single step. The exceptionally mild conditions required for this traceless transformation are in stark contrast with previous methods requiring the use of harsh thermal conditions.

History

Email Address of Submitting Author

davide.audisio@cea.fr

Institution

Université Paris Saclay, CEA

Country

France

ORCID For Submitting Author

0000-0002-6234-3610

Declaration of Conflict of Interest

No conflict of interest

Exports