A Kinetic Description of How Interfaces Accelerate Reactions in Micro-Compartments

Kevin Wilson; Alexander Prophet; Grazia Rovelli; Megan Willis; Rebecca Rapf; Michael Jacobs

doi:10.26434/chemrxiv.12506117.v1

Physical Chemistry

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A Kinetic Description of How Interfaces Accelerate Reactions in Micro-Compartments

25 June 2020, Version 1

Working Paper

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This content is a preprint and has not undergone peer review at the time of posting.

Abstract

A kinetic expression is derived to explain how interfaces alter bulk chemical equilibria and accelerate reactions in micro-compartments. This description, aided by the development of a stochastic model, quantitatively predicts previous experimental observations of accelerated imine synthesis in micron-sized emulsions.

Keywords

reaction acceleration

Microdroplets

Microcompartments

emulsions microenvironment

Stochastic simulations

Surface reaction mechanism

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Jun 25, 2020 Version 1

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The content is available under CC BY NC ND 4.0

DOI

10.26434/chemrxiv.12506117.v1

Funding

DE-AC02-05CH11231

Author’s competing interest statement

no conflict of interest

A Kinetic Description of How Interfaces Accelerate Reactions in Micro-Compartments

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Abstract

Keywords

Comments

Version History

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DOI

Funding

Author’s competing interest statement

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