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Plunkett - Biaceanthrylenes ChemRxiv 08-01-19.pdf (1.39 MB)
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1,1’-Biaceanthrylene and 2,2'-Biaceanthrylene: Models for Linking Larger Polycyclic Aromatic Hydrocarbons via Five-Membered Rings

preprint
submitted on 02.08.2019 and posted on 02.08.2019 by Yachu Du, Kyle Plunkett
We show that polycyclic aromatic hydrocarbon (PAH) chromophores that are linked between two five-membered rings can access planarized structures with reduced optical gaps and redox potentials. Two aceanthrylene chromophores were connected into dimer model systems with the chromophores either projected outward (2,2’-biaceanthrylene) or inward (1,1’-biaceanthrylene) and the optical and electronic properties were compared. Only the planar 2,2’-biaceanthrylene system showed significant reductions of the optical gaps (1 eV) and redox potentials in relation to the aceanthrylene monomer.

Funding

CAREER: Electron Acceptor Materials Based on Cyclopenta-fused Polycyclic Aromatic Hydrocarbons

Directorate for Mathematical & Physical Sciences

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History

Email Address of Submitting Author

kplunkett@chem.siu.edu

Institution

Southern Illinois University

Country

United States

ORCID For Submitting Author

0000-0002-5691-7876

Declaration of Conflict of Interest

No conflict of interest

Version Notes

Presubmission

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