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Well defined Au(III)-bisfluorides supported by N-ligands

30 January 2018, Version 1
Working Paper
This content is a preprint and has not undergone peer review at the time of posting.

Abstract

Oxidation of bis-N ligatated Au(I) cations using XeF2 gives well
defined cationic trans bisfluorides of Au(III). X-ray crystallographic
studies of the bisimidazole ligated derivative shows the shortest
Au-F bond known in a gold complex.

Keywords

Gold
Fluorine
Chemistry

Supplementary materials

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Description
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Now Published

Well defined difluorogold(iii) complexes supported by N-ligands [opens in a new tab]
Mohammad Albayer, Robert Corbo, Jason L. Dutton journal article
Chemical Communications , Volume 54, Issue 50
Online publication date: 2018

Version History

Jan 30, 2018 Version 1

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The content is available under CC BY NC ND 4.0 [opens in a new tab]

DOI

10.26434/chemrxiv.5830779.v1
D O I: 10.26434/chemrxiv.5830779.v1 [opens in a new tab]

Funding

Australian Research Council

Author’s competing interest statement

None.

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